Exploiting electron storage in TiO2 nanoparticles for dark reduction of As(V) by accumulated electrons.

نویسندگان

  • Ivana K Levy
  • Marta A Brusa
  • Matias E Aguirre
  • Graciela Custo
  • Enrique San Román
  • Marta I Litter
  • María A Grela
چکیده

UV irradiation of an ethanolic sol of TiO2 nanoparticles produces a trapped Ti(III) centre and a noticeable Burstein shift. Direct evidence that the accumulated charges can drive the otherwise forbidden reduction of As(V) by conduction band electrons is presented.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 15 25  شماره 

صفحات  -

تاریخ انتشار 2013